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High Bioavailability : By avoiding the gastrointestinal tract and first-pass metabolism in the liver, drugs administered through the lungs can achieve higher bioavailability compared to oral administration (Although first-pass metabolism may occur in the lungs as well as other metabolically active tissues)

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Functions : Neutralizes free radicals (protects against cellular damage) Helps regenerate other antioxidants (like vitamins C and E) Supports liver detoxification processes Plays a role in DNA synthesis and repair, and protein synthesis Forms : Reduced glutathione (GSH) : The active form that acts as an antioxidant Oxidized glutathione (GSSG) : Formed when GSH donates electrons and becomes oxidized Glutathione and Health: Low levels are linked to conditions like Parkinsons disease , Alzheimers , chronic fatigue , liver disease , and cancer

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The spirosuccinimide of ( S )-dHTC1 engages the IMiD-binding site of CRBN but, interestingly, it adopts a slightly different pose in the ternary complex compared to what was revealed by the cocrystal structure of the binary complex (Extended Data Fig